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Molality is a measure of concentration in chemistry, expressed as the amount of solute in moles divided by the mass of the solvent in kilograms. It is based on the mole, a fundamental chemical unit defined as containing the same number of units as the number of atoms in 12 grams of carbon-12. Molality is often more reliable than molarity, which is based on volume, in situations where the temperature of the solution is variable.
Molality is a ratio used in analytical chemistry to express quantitatively the concentration of a chemical solution. When a solution is made, it contains a certain amount of solute, a substance that dissolves in a liquid. The liquid in which the solute is dissolved is known as the solvent. Molality (m) is the amount of solute, expressed in units called moles, divided by the mass of the solvent in kilograms.
To understand molality, you need to understand the mole, a fundamental chemical unit. One mole of a substance is defined as containing the same number of units as the number of atoms in 12 grams (g) of the element carbon-12. This very large number is known as Avogadro’s number. One mole of carbon-12, by definition, therefore weighs 12 grams.
All other atomic masses of the elements are based on the carbon-12 standard. A unified atomic mass unit (u) is equal to 1/12 the mass of a carbon-12 atom – carbon-12 weighs 12 u. The mole is defined this way purely for convenience. Mathematically, it means that the mass of one mole of a compound in grams equals its molecular mass in u.
The molecular mass of a compound can be found by adding up the atomic masses of its constituent atoms. For example, water is made up of two hydrogen atoms and one oxygen atom. Each hydrogen atom has an atomic mass of about 1.008 u and the mass of oxygen is about 15.999 u. The molecular mass of water is therefore approximately 18.015 u, and the mass of one mole of water is 18.015 g.
The amount of a solute in a chemical solution is measured in moles. One mole of salt, also known as sodium chloride, has a mass of approximately 58.5 g. If 58.5 g or one mole of salt were dissolved in one kilogram of water, the resulting solution would have a molality of 1 m. Furthermore, if two moles of sodium chloride were dissolved in 5 kilograms of water, the molality would be 4 m.
A similar and more widely used measure of concentration is molarity (M). Molarity, unlike molality, is based on volume: it is the number of moles of a solute in one liter of solution. Because the volume of a solution can change—expand or contract with changes in temperature—molarity isn’t always a reliable measure of concentration. Molality, which is based on the immutable amount of mass, is often most useful in situations where the temperature of the solution is variable.
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